Photochemically driven addition of iminyl radicals to alkynyl Fisher carbene complexes
- Blanco-Lomas, M. 1
- Caballero, A. 1
- Campos, P.J. 1
- González, H.F. 1
- López-Sola, S. 1
- Rivado-Casas, L. 1
- Rodríguez, M.A. 1
- Sampedro, D. 1
-
1
Universidad de La Rioja
info
ISSN: 0276-7333
Año de publicación: 2011
Volumen: 30
Número: 13
Páginas: 3677-3682
Tipo: Artículo
Otras publicaciones en: Organometallics
Resumen
Nitrogen-centered radicals, generated by the action of UV light, are capable of reacting with alkynyl Fischer carbene complexes in two ways, 1,2- and 1,4-addition. Our results constitute the first reported example of a photochemically driven reaction of this kind. © 2011 American Chemical Society.